Q.
Two volatile liquids A and B are mixed in the mole ratio 3 : 2 to form an ideal solution. Vapour pressure of pure liquids A and B is 600 mm Hg and 300 mm Hg respectively. Mole fraction of B in vapour phase is
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a
0.66
b
0.33
c
0.25
d
0.4
answer is C.
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Detailed Solution
Mole fraction in liquid mixtureXA=35 ; XB=25Given pAo=600 mm ; pBo=300 mmAccording to Raoult's law Ptotal=pAoXA+pBoXBPtotal=60035+30025Ptotal=360+120mmIn vapour phase, applying Dalton's lawpB=ptotal×yByB=pBptotalyB=120480yB=0.25
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