First slide

Structural isomerism

Question

The type of isomerism shown by $[Co {(en)}_{2} {(NCS)}_{2}] Cl$ and $[Co {(en)}_{2} (NCS) Cl] NCS$ is:

Easy

A

ionization
B

coordination
C

linkage
D

all of these

Solution

On ionization different species are formed to show ionization isomerism:
$\begin{array}{l} [Co {(en)}_{2} {(NCS)}_{2}] Cl ⇌ {[CO ({en}_{2}) {(NCS)}_{2}]}^{+} + {Cl}^{-} \\ [Co {(en)}_{2} (NCS) Cl] NCS ⇌ {[CO {(en)}_{2} (NCS) Cl]}^{+} + {NCS}^{-} \end{array}$

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