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Q.

Type of isomerism which is shown by PtCl2Br22− is also observed in:

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a

CoCl2Br22−

b

Coen33+

c

PtCl4Br22−

d

PtCl3NO22−

answer is C.

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Detailed Solution

Square planar [PtCl2Br2]2- = Show GI(a) Tetrahedral [CoCl2Br2]2- = Does not show GI(b) Octahedral [Co(en)3]3+ = Show optical isomerism(c) Octahedral [PtCl4Br2]2- = Show GI(d) [PtCl3(NO2)]2- = This belongs to MA3B, so does not show GI
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