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Q.

Under what conditions will a pure sample of an ideal gas not only exhibit a pressure of 1 atm but also a concentration of 1 mole  litre −1R=0.082 litre atmmol 1deg−1

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a

At STP

b

When V = 22.4 litres

c

When T = 12K

d

Impossible under any conditions

answer is C.

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Detailed Solution

PV=nRTP=nVRT ∵nV=C⇒P=CRTT=PCR=11×0.0821=12K rN2rSO2=VrmsN2VrmsSO2=TN2TSO2.MSS2MN2=TN2323×64281.625=TN2323⋅167TN2=(1.625)2×323×716=373K
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