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Q.

In the unit cell of KCI (NaCl type), Cl- ions constitute ccp and K+ ions fall into the octahedral holes. These holes are:

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a

one at the centre and 6 at the centres of the faces

b

one at the centre and 12 at the centres of the edges

c

8 at the centres of 8 small cubes forming the unit cell

d

12 at the centre and 1 at edge face

answer is B.

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Detailed Solution

Octahedral sites in fcc are present at each edge centre as well as at body centre.
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