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Q.

Unsubstituted organic acids are weak (or) very weak acids. Which of the following compound is most acidic?

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a

CH3−CH3

b

CH≡CH

c

CH3−C≡CH

d

CH2=CH2

answer is B.

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Detailed Solution

Electronegativity of Csp>Csp2>Csp3. Greater the stability of the anion after the loss of proton stronger is the acid.More electronegative atom can hold negative charge most readily. ∴stability  of  HC≡C⊝>CH3−C≡C⊝>CH2=C⊝H>CH3−C⊝H2    stability   of  CH≡C⊝>CH3−C≡C⊝  because+I effect of -CH3 group intensifies the negative charge and destabilizes the carbanion.
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