Q.
Using the data provided, calculate the multiple bond energy (kJ mol-1) of a C ≡ C bond in C2H2.Given that the heat of formation of C2H2 = 225 kJ mol-1.(take the bond energy of a C - H bond as 350 kJ mol-1)
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a
1165
b
837
c
865
d
815
answer is D.
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Detailed Solution
i) 2C(s)+H2(g)⟶H−C≡C−H(g) ΔH=225kJmol−1ii) 2C(s)⟶2C(g) ΔH=1410kJmol−1iii) (iii) H2(g)⟶2H(g) ΔH=330kJmol−1 From equation (i):225=[1410+1×330]−2×350+1×eC≡C225=[1410+330]−700+eC≡C225=1740−700−eC≡CEC≡C=1040−225=815kJmol−1BEC≡C=815kJmol−1
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