The value of angle strain (potential energies) between the two extreme conformations of ethane is:
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a
10.5 k J mol–1
b
12.5 k J mol–1
c
14.0 k J mol–1
d
44.0 k J mol–1
answer is B.
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Detailed Solution
The energy of the eclipsed conformation is approximately 3 kcal/mol (12 kJ/mol) higher than that of the staggered conformation. Torsional strain (or eclipsing strain) is the name give to the energy difference caused by the increased electrostatic repulsion of eclipsing bonds.