Q.
The value of rate constant of a pseudo first order reaction
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a
Depends only on temperature
b
Depends on the concentration of reactants present in small amounts
c
Depends on the concentration of reactants present in excess
d
Is independent of the concentration of reactants
answer is C.
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Detailed Solution
A Higher order reaction converted into lower order by taking one of the reactant in large excess is called as pseudo order reaction.consider reaction A+2B→productsrate=kAB2B is taken in large it does not influence rate of reaction KB2 is constant.rate=k'A,where K'=kB2 3rd order is converted into 1st order and rate constant depends on B taken in large excess.
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