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Q.

Vapour density of the equilibrium mixture of the reaction SO2Cl2(g)  ⇆   SO2(g)  +  Cl2(g) is 50. The extent of dissociation of SO2Cl2(g)  is

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a

33.33%

b

66.67%

c

30.0%

d

35.0%

answer is D.

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Detailed Solution

50=64+711+α = 1351+αor     1+α  =  1352 × 50= 1.35α  = 0.35  ⇒  35.0%
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Vapour density of the equilibrium mixture of the reaction SO2Cl2(g)  ⇆   SO2(g)  +  Cl2(g) is 50. The extent of dissociation of SO2Cl2(g)  is