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Q.

The vapour density of PCl5 is 104.25 but when heated to 230oC, its vapour density is reduced to 62. The degree of dissociation of PCl5 at this temperature will be

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a

6.8%

b

68%

c

46%

d

64%

answer is B.

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Detailed Solution

PCl5(g)  ⇌  PCl3(g)  +  Cl2(g)1+α = Dd1+α = 104.2562              1+α =1.68∴       α  = 0.68   or     68%
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