Q.

A vessel contains 1 mole PCl5 (g) at 4 atm and 0.5 mole PCl3 formed at equilibrium. Now, equilibrium pressure of mixture is (assume ideal behavior)

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a

16 atm

b

6 atm

c

2 atm

d

4.5 atm

answer is B.

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Detailed Solution

p ∞n (V,T are constant)initial moles = 1 mole at equilibrium total moles = (1-0.5)+0.5+0.5 = 1.5pinitialpfinal =ninitial nfinal 4pf=11.5 Equilibrium pressure of the mixture  = pf =1.5×4 = 6 atm
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