Q.

A vessel contains N2O4 & NO2 in 2:3 molar ratio at 10 atm under equilibrium. Now, KP for  is

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a

9 atm

b

9 atm-1

c

4.5 atm2

d

10 atm

answer is A.

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Detailed Solution

Partial pressure of N2O4 at equilibrium = χN2O4×Peq = 25×10 = 4 atmPartial pressure of NO2 at equilibrium =  χNO2×Peq  =  35×10  = 6 atmKP = PNO22PN2O4=6×64=9 atm
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