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Q.

A vessel at 1000 K contains CO2 with a pressure of 0.5 atm. Some of the CO2 is converted into CO on the addition of graphite. If the total pressure at equilibrium is 0.8 atm, the value of K is

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answer is 1.8.

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Detailed Solution

Given total pressure = 0.8 atmCO2(g) + C(s) ⇌ 2CO(g)Total pressure = 0.5-P +2P = 0.8P = 0.8-0.5 = 0.3KP = P2CO/PCO2 = (2P)2/(0.5-P)= (0.6)2/0.2= 0.36/0.2= 1.8 atm
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A vessel at 1000 K contains CO2 with a pressure of 0.5 atm. Some of the CO2 is converted into CO on the addition of graphite. If the total pressure at equilibrium is 0.8 atm, the value of K is