Q.

What are the products obtained when PCI3 reacts with water (i) cold condition (ii) hot condition?

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a

H3PO4+PH3;H3PO3

b

H3PO3; H3PO4+PH3

c

PO4Cl3+H2;H3PO4+H2

d

H3PO3;POCl3+H2

answer is B.

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Detailed Solution

(i) PCl3+3H2O→Cold3HCl+H3PO3ii PCl3+3H2O→Δ3HCl+H3PO34H3PO3→200oC3H3PO4+PH3
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