Q.
What are the products obtained when PCI3 reacts with water (i) cold condition (ii) hot condition?
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a
H3PO4+PH3;H3PO3
b
H3PO3; H3PO4+PH3
c
PO4Cl3+H2;H3PO4+H2
d
H3PO3;POCl3+H2
answer is B.
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Detailed Solution
(i) PCl3+3H2O→Cold3HCl+H3PO3ii PCl3+3H2O→Δ3HCl+H3PO34H3PO3→200oC3H3PO4+PH3
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