Q.

What % of the carbon in the H2CO3 - HCO3- buffer should be in the form of HCO3- so as to have a neutral solution ? Ka= 4 × 10-7

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a

20%

b

40%

c

60%

d

80%

answer is D.

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Detailed Solution

pH=pKa + log HCO3-H2CO3 ⇒  7=7-log 4 + log  HCO3-H2CO3⇒HCO3-H2CO3=4 %  of carbon in the form of HCO3- = HCO3-HCO3-H2CO3 × 100 = 41+4 × 100=80%
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What % of the carbon in the H2CO3 - HCO3- buffer should be in the form of HCO3- so as to have a neutral solution ? Ka= 4 × 10-7