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Q.

What may be expected to happen when phosphine gas is mixed with chlorine gas.

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a

The mixture only cools down

b

PCl3 and HCl are formed and the mixture warms up

c

PCl5 and HCl are formed and the mixture cools down

d

PH3 and Cl2 is formed with warming up

answer is B.

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Detailed Solution

PH3+3Cl2→PCl3+3HCl (exothermic) make the solution warm option (c) is not possible because its show the endothermic reaction.
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What may be expected to happen when phosphine gas is mixed with chlorine gas.