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Q.

What is the order of reaction for which rate becomes half if volume of the container having same amount of reactant is doubled? Assume gaseous phase reaction.

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answer is 1.

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Detailed Solution

Rate =k[a]nCase I : r1=kaVn            . . . (i) Case II: r12=ka2Vn       . . . (ii)By Eqs. (i) and (ii)21=2n ∴  n = 1
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What is the order of reaction for which rate becomes half if volume of the container having same amount of reactant is doubled? Assume gaseous phase reaction.