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Q.

What is the pressure of 2 mole of  NHa at 27∘C when its volume is 5 litre in Vander Waals equation  (a=4.17,b=0.037111

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a

10.33 atm

b

9.33 arm

c

9.74 atm

d

9.2 arm

answer is B.

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Detailed Solution

P−n2aV2(V−nb)=nRTP−(2)2×4.17(5)2(5−2×.03711)=2×.0821×300P=2×.0821×3005−2×.03711−4.7×2252⇒10−0.66=9.33atm
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