What will happen when D-(+)-glucose is treated with methanolic HCI followed by Tollen's reagent?
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a
A black ppt. will be formed
b
A red ppt. will be formed
c
A green colour will appear
d
No characteristic colour or ppt. will be formed.
answer is D.
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Detailed Solution
Reaction of D-(+)-glucose with methanolic –HCl leads to formation of methyl glucoside (C1-OH group is methylated which, being acetal. Is not hydrolysable by base, so it will not respond Tollen's reagent.