When applied external opposite potential in case of Daniell cell is less than 1.1 V, then

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the cell behaves like an electrolytic cell

electrons flow from zinc rod to copper rod

zinc deposites at the zinc electrode and copper dissolves from copper rod

Current flow from zinc rod to copper rod

answer is B.

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Detailed Solution

When Eext<1.1 V(i) Electrons flow from zinc electrode to copper electrode,hence, current flows from copper to zinc electrode.(ii) Zinc dissolves at anode and copper deposites at cathode.

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