Q.

When aqueous sodium chloride solution is electrolysed

see full answer

Want to Fund your own JEE / NEET / Foundation preparation ??

Take the SCORE scholarship exam from home and compete for scholarships worth ₹1 crore!*
An Intiative by Sri Chaitanya

a

at cathode H+ is reduced into H2 instead of Na+

b

at cathode Na+ is reduced to Na

c

Cl- is oxidised into Cl2 at cathode

d

Both (b) and (c)

answer is A.

(Unlock A.I Detailed Solution for FREE)

Ready to Test Your Skills?

Check your Performance Today with our Free Mock Test used by Toppers!

Take Free Test

Detailed Solution

When aqueous solution of NaCl is electrolysed, there is a competition between the following reductions reactions at cathode                    Na++e−⟶Na;Ecell∘=−2.71VH++e−⟶12H2;Ecell∘=0.00VThe reaction with higher value of Eo is preferred and therefore, the second reaction occurs at cathode, i.e. H+ is reduced instead of Na+ .
Watch 3-min video & get full concept clarity
ctaimg

Get Expert Academic Guidance – Connect with a Counselor Today!

+91

Connect with our

Expert Counsellors

access to India's best teachers with a record of producing top rankers year on year.

+91

We will send a verification code via OTP.

whats app icon