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Q.

When aqueous sodium chloride solution is electrolysed

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a

at cathode H+ is reduced into H2 instead of Na+

b

at cathode Na+ is reduced to Na

c

Cl- is oxidised into Cl2 at cathode

d

Both (b) and (c)

answer is A.

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Detailed Solution

When aqueous solution of NaCl is electrolysed, there is a competition between the following reductions reactions at cathode                    Na++e−⟶Na;Ecell∘=−2.71VH++e−⟶12H2;Ecell∘=0.00VThe reaction with higher value of Eo is preferred and therefore, the second reaction occurs at cathode, i.e. H+ is reduced instead of Na+ .
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When aqueous sodium chloride solution is electrolysed