When aqueous solution of sodium ethanoate is electrolysed, the volume of gases obtained at cathode at apressure of 1.0 bar and 298 K temperature when 2.0 Faraday of electricity is passed is:
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a
67.2 litres
b
68.1 litres
c
73.2 litres
d
7 4.1 litres
answer is D.
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Detailed Solution
For 2e- or 2F,3 mol of gases 12 mol of CO2, + 1 mol of CH3-CH3 (g)l are produced.At 1.0 bar pressure and 298 K, volume of 1 mol of gas :24.7 litres.∴ Volume of gases at anode = 24.7 x 3 : 74.L litres