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Q.

When Cl2 water is added to an aqueous solution of potassium halide in presence of chloroform a violet colour is obtained. On adding more of Cl2 water, the violet colour disappears and a colorless solution is obtained. This test confirms presence of following in aqueous solution :

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a

Bromide

b

Chloride

c

Iodide and bromide

d

Iodide

answer is D.

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Detailed Solution

2KI+Cl2→I2+2KCl I2+CCl4→ violetI2+5Cl2(Excess)+6H2O→2HIO3+10HCl violet colour disappear

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When Cl2 water is added to an aqueous solution of potassium halide in presence of chloroform a violet colour is obtained. On adding more of Cl2 water, the violet colour disappears and a colorless solution is obtained. This test confirms presence of following in aqueous solution :