Q.

When CH3COOC2H5was hydrolysed in presence of the rate constant obtained as 5.40×10−5s−1.But when 0.1MH2SO4 was fused for hydrolysis, the rate constant obtained as 6.20×10−5s−1. From these it can be said that

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a

H2SO4 is stronger than HCI

b

H2SO4 is weaker than HCI

c

Both HCI and H2SO4 are of same strength

d

insufficient data to compare the strength of H2SO4 and HCl

answer is D.

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Detailed Solution

The strengths of two acids can be compared only by knowing their dissociation constants.
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When CH3COOC2H5was hydrolysed in presence of the rate constant obtained as 5.40×10−5s−1.But when 0.1MH2SO4 was fused for hydrolysis, the rate constant obtained as 6.20×10−5s−1. From these it can be said that