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Q.

When 2g of a gas A is introduced into an evacuated flask kept at 25ºC, the pressure is found to be 1 atmosphere. If 3g of another gas is then added to the same flask, the total pressure becomes 1.5 atm. Assuming ideal behaviour, the ratio of their molecular weights MA : MB is

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a

3 : 1

b

1 : 3

c

2 : 3

d

3 : 2

answer is B.

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Detailed Solution

n α P V,T are constant nAPA=nBPB=wBMBxPB=wAMAxPA MAMB=2x0.53x1=13     (Since pressure of gas B (PB)  = 1.5 - 1 = 0.5)
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