Q.

When HCl is added on to propene in presence of peroxide the intermediate formed is

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a

CH3C+HCH3

b

CH3CH2C+H2

c

CH3C•HCH2Cl

d

CH3CH2C•H2

answer is A.

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Detailed Solution

HCl does not add on to propene by peroxide effect. Even in presence of peroxide the addition is according to Markownikoff’s rule forming intermediate carbonium ion.
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