Q.

when heated, ammonium carbamate decomposes as follows NH4COONH2(s)⇌2NH3(g)+CO2(g) At a certain temperature, the equilibrium pressure of the system is 0.318 arm. K p for the reaction is :

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a

0.128

b

0.426

c

4.76×10−3

d

None of these

answer is C.

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Detailed Solution

Ptotal =3P ⇒  P=0.3183=0.106 ∴  Kp=4P3=4.76×10-3
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when heated, ammonium carbamate decomposes as follows NH4COONH2(s)⇌2NH3(g)+CO2(g) At a certain temperature, the equilibrium pressure of the system is 0.318 arm. K p for the reaction is :