Q.
When a mixture containing PCl3 and PCl5 is heated with excess C2H5OH total of 4 moles of C2H5Cl is formed. Mole ratio of PCl3 and PCl5 in the mixture is
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a
3:1
b
1:3
c
1:1
d
2:1
answer is C.
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Detailed Solution
3C 2H5OH+PCl3→Δ3C2H5−Cl+H3PO3C2H5OH + PCl5 −→ C2H5−Cl + H−Cl + POCl3
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