Q.

When a mixture containing PCl3  and PCl5  is heated with excess C2H5OH  total of 4 moles of C2H5Cl  is formed. Mole ratio of PCl3  and PCl5  in the mixture is

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a

3:1

b

1:3

c

1:1

d

2:1

answer is C.

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Detailed Solution

3C 2H5OH+PCl3→Δ3C2H5−Cl+H3PO3C2H5OH + PCl5 −→ C2H5−Cl + H−Cl + POCl3
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