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Q.

When O2 is adsorbed on a metallic surface, electron transfer occurs from the metal to O2. The TRUE statement(s) regarding this adsorption is(are)

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a

O2 is physi-absorbed

b

heat is released

c

occupancy of π2p* of  O2 is increased

d

bond length of  O2 is increased

answer is B.

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Detailed Solution

During transfer of e- adsorption is exothermic. During Electronic transfer metal to π∗2p of O2 of  molecule Bond order of O2 decreases, and hence increasing O-O bond length.
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