Q.

When phenol is reacted with CHCI3 and NaOH followed by acidification, salicylaldehyde is obtained. Which of the following species are involved in the above mentioned reaction as intermediate?

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a

b

c

d

answer is D.

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Detailed Solution

Riemer-Tiemann reaction involves electrophilic substitution on the highly reactive phenoxide ring.HCCl3+OH−→H2O+−:CCl3
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When phenol is reacted with CHCI3 and NaOH followed by acidification, salicylaldehyde is obtained. Which of the following species are involved in the above mentioned reaction as intermediate?