Which of the alkaline earth metals cation has least hydration enthalpy ?
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a
Be2+
b
Mg2+
c
Ca2+
d
Ba2+
answer is D.
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Detailed Solution
Be2+ > Mg2+ > Ca2+ > Sr2+ > Ba2+ : Size of isolated M+2 ionsBe2+ > Mg2+ > Ca2+ > Sr2+ > Ba2+ : Degree of hydrationBe2+ > Mg2+ > Ca2+ > Sr2+ > Ba2+ : Hydration EnthalpiesAs the size of M+2 ions [isolated] increases effective nuclear charge on the ion decreases nuclear attractive forces on the water molecules decreases, number of water molecules surrounded around the M+2 ion decreases degree of hydration decreases hydration enthalpy decreases