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Q.

Which among the following has the highest volatility ?

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a

H2O

b

H2S

c

H2Se

d

H2Te

answer is B.

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Detailed Solution

Boiling point α 1VolatilityB.Pt order : H2S < H2Se < H2Te < H2OBoiling point orderFrom →H2S to H2Te As the size of central atom increases,size of molecule [or MWT] increases , and hence intermolecular attractions between the molecules increases.Inorder to break up those attractions we need to provide more amount of energy in the form of B.Pt [heat]H2O possess exceptionally hight B.Pt among all the VIA group hybrides, due to its ability to form intermolecular hydrogen bonding∴ The volatility order is →H2S > H2Se >H2Te >H2OAs the B.Pt increases, volatility decreases.Note :- Volatility is the property of a compound, how  easily it undergoes vapourisation.
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