Which among the following will give 3,3–dimethylbut–1–yne on reaction with NaNH2/∆
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a
1,4–dibromo–3,3–dimethylbutane
b
2,2–dibromo–3,3–dimethylbutane
c
1,2–dibromo–3,3–dimethylbutane
d
Both (2) and (3)
answer is D.
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Detailed Solution
1,2–dibromo–3,3–dimethylbutane undergo dehydrohalogenation reaction in the presence of NaNH2 in liquid NH3 and forms 3,3–dimethyl but–1–yne.2,2–dibromo–3,3–dimethylbutane undergo dehydrohalogenation reaction in the presence of NaNH2 in liquid NH3 and forms 3,3–dimethylbut–1–yne.