Q.
Which are true for the reaction : A2⇌2C+D?
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a
if ∆H=0; Kp and α (alpha) increases with increase in temperature
b
if ∆H=+ve, Kp increases with temperature and dissociation of A2 increases.
c
if ∆H=-ve, Kp decreases with temperature and dissociation of A2 decreases.
d
Kp=4α3P1+2α2
answer is A.
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Detailed Solution
A ⇌ 2C + D Initial 1 0 0 At equilibrium 1-α 2α α Kp =(2α)2α×P∆n2=4α3P21+2α2 Use 2.303 log K2K1=∆HRT2-T1T1T2 for effect of temperature on K.
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