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Q.

Which is expected to react most readily with bromine

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a

CH3CH2CH3

b

CH2=CH2

c

CH≡CH

d

CH3-CH=CH2

answer is A.

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Detailed Solution

Halogen addition is electrophilic addition and increasing order of reactivity towards halogen addition isAlkane > Alkyne < AlkeneAlkynes are less reactive than alkene towards addition of halogen, the intermediate formed in case of alkyne is less stable :In alkenes, more substituted alkenes are reactive towards Br2/Cl2.
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