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Q.

Which of the following alkaline earth metal sulphates has hydration enthalpy higher than the lattice enthalpy ?

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a

CaSO4

b

BeSO4

c

BaSO4

d

SrSO4

answer is B.

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Detailed Solution

Smaller the size of cation, higher is the enthalpy of hydration.as we move down the group both hydration enthalpy  and lattice dissociation  energy decrease but decrease in hydration enthalpy is more so solubility decreases
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