Which of the following applies correctly to toluene?
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a
When heated with chlorine in light benzyl chloride is formed
b
When treated with Cl2 in presence of ZnCl2 , ortho and para chlorotoluenes are formed
c
When heated with AICI3 alone, it undergo disproportionation
d
When treated with concentrated HNO3 in presence of concentrated sulphuric acid, all three isomeric nitrotoluenes are formed with their relative yield-para> meta>ortho
answer is A.
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Detailed Solution
.toluene shows benzylic chlorination, methyl group is an electron donating group hence toluene is o, p director