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Q.

Which of the following applies correctly to toluene?

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a

When heated with chlorine in light benzyl chloride is formed

b

When treated with Cl2 in presence of ZnCl2 , ortho and para chlorotoluenes are formed

c

When heated with AICI3 alone, it undergo disproportionation

d

When treated with concentrated HNO3 in presence of concentrated sulphuric acid, all three isomeric nitrotoluenes are formed with their relative yield-para> meta>ortho

answer is A.

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Detailed Solution

.toluene shows benzylic chlorination, methyl group is an electron donating group hence toluene is o, p director
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