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Q.

Which of the following are diastereomers?

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a

(I) and (III

b

(II) and (IV)

c

(I) and (II)

d

None

answer is C.

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Detailed Solution

The Fischer projection of (I) and (II) is wrong because the functional group is not at the top. on rotating (I) and (II) by 180°, they are represented as shown:Now compare I, II, III, and IV.(I) and (III) ⇒ Enantiomers(II) and (IV) ⇒Identical or sameTherefore, the pairs of diastereomers are:(I), (II) (D, (IV); and (II), (III).But the answer given is (3) (I, II).
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