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Which of the following Aromatic electrophilic substitution reaction(A.E.S.R) is impossible to occur ?

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a
Chlorination of Benzene
b
Bromination of Benzene
c
Iodination of Benzene
d
Fluorination of Benzene

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detailed solution

Correct option is D

Since A.E.S.R involves positive species as follows and  Positive charged Florine is not-possible,

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