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Q.

Which of the following can give a positive test with 2, 4-D.N.P and negative test with tollens reagent, and can also react with NaOI to give an yellow ppt

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a

CH3−CHO

b

CH3−CH2−COOH

c

CH3−CH2−CO−CH3

d

CH3−CH(OH) −CH3

answer is C.

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Detailed Solution

Positive test with 2, 4-D.N.P = carbonyl compound         Negative test with tollens reagent = ketone      NaOI   giving iodoform = Methyl keto compounds
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Which of the following can give a positive test with 2, 4-D.N.P and negative test with tollens reagent, and can also react with NaOI to give an yellow ppt