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Q.

Which of the following carbo cations is least stable?

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a

PhCH⊕2

b

CH⊕=CH2

c

Me2CH⊕

d

CH2=CH−CH⊕2

answer is B.

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Detailed Solution

Reason: The stability of  a  carbon cation  decreases as we go from sp3 to   to sp .Compared to sp3,  sp2  there is more S-Character  in orbitals, so the empty  orbital  is held more closely to the nucleus. so option (2) is correct. It has less stable.
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