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Q.

In which of the following case, there is no effect of dilution on pH?

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a

0.01MCH3COONa+0.01MCH3COOH buffer

b

0.01MCH3COONH4+0.01M NaOH

c

0.01 M NaH2PO4+0.01 M NaOH

d

0.01 LiOH + 0.01 LiCN

answer is A.

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Detailed Solution

.An acidic buffer solution is simply one which has a pH less than 7. Acidic buffer solutions are commonly made from a weak acid and one of its salts - often a sodium salt. A common example would be a mixture of ethanoic acid and sodium ethanoate in solution.
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