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Q.

Which of following complex has higher Δo value ?

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a

FeH2O63+

b

FeH2O62+

c

Fe(H2O)63−

d

all have equal

answer is C.

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Detailed Solution

[Fe(H2O)6]3+ Fe has an oxidation state of +3.Δo=(−2/5)3+3/5∗2=0[Fe(H2O)6]2+ Fe has an oxidation state of +2.Δo=(−2/5)4+3/5∗2= −0.4[Fe(H2O)6]3− Fe has an oxidation state of −3.Δo=(−2/5)6+3/5∗3= −0.6

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Which of following complex has higher Δo value ?