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Which of the following complex is inner orbital as well as low spin complex?

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By Expert Faculty of Sri Chaitanya
a
CrH2O63+
b
Fe(CN)63−
c
Cu(CN)43−
d
MnNH362+

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detailed solution

Correct option is B

CrIIIH2O63+; Hybridisation: d2sp3Inner orbital complexFe+III(CN)63−;P<Δ0: Hybridisation: d2sp3Inner orbital / low spin / spin paired complex.Cu+I(CN)43−; Hybridisation : sp3MnH2O62+P<Δ0: Hybridisation: sp3d2Outer orbital / high spin / spin free complex


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