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Q.

In which of the following complex ion the value of magnetic moment (spin only) is 3 BM and outer d-orbitals is used in hybridization.

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a

Mn(CN)64−

b

FeNH363+

c

Co(CO)4

d

CuH2O62+

answer is D.

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Detailed Solution

Mn(CN)64−: Hyb. :d2sp3,μeff=3 B.M. FeNH363+: Hyb. :d2sp3,μeff=3 B.M. Co(CO)4:Hyb:dsp2,μeff=3 B.M CuH2O62+: Hyb. :sp3d2,μeff=3 B.M
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