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Q.

Which of the following complex ion/compound is low spin complex?

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a

Cr(CO)6

b

Zn(CN)42−

c

ScNH362+

d

CoF63−

answer is A.

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Detailed Solution

⇒Cr(CO)6                  : Hyb. d2sp3  Low spin complex ⇒Zn(CN)42−              : Zn2+ is present as 3d10      ⇒ScNH363+            : Sc3+ is present as 3d0           ⇒CoF63−                    : Co3+ is present as 3d6-WFL is present
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