Q.

In which of the following complex while naming the complex, the suffix “-ate” is used after the name of the central metal ion

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a

Nien3Cl2

b

CoNH33Cl3

c

CrH2O62SO43

d

K3FeCN6

answer is D.

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Detailed Solution

The suffix “-ate” is used after the name of the complex only in anionic complexes;Options 1,3 are cationic complexes whereas option 2 is a neutral complex;Only option 4 is an anionic complex;K3FeCN6⇌3K++FeCN6-3; Potassium hexacyanido ferrate(III) is its IUPAC name;
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In which of the following complex while naming the complex, the suffix “-ate” is used after the name of the central metal ion