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Which of the following complexes formed by Cu+2 ion is most stable

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By Expert Faculty of Sri Chaitanya
a
Cu+2+4NH3⇌CuNH342+ ;  logK=11.6
b
Cu+2+4CN−⇌CuCN42− ; logK=27.3
c
Cu+2+2en⇌Cuen22+ ; logK=15.4
d
Cu+2+4H2O⇌CuH2O42+ ; logK=8.9

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detailed solution

Correct option is B

All the equations denote the formation of complexes.Greater the value of stability constant (k), greater will be the stability of complex.Stability of (2) > (3) > (1) > (4).


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Statement 1: K2NiEDTA is more stable than K3AlC2O43.

Statement 2: Nickel (Ni) is a transition element while aluminium (Al) is non-transition element.

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