Which of the following complex(s) cannot exhibit both geometrical and optical isomerism?
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a
[Co(H2O)Br3]
b
[PtBrC1FI]-2
c
[FeC12(en)2]⊕
d
[Ru(en)3]+3
answer is A.
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Detailed Solution
⇒sp3hybridisation; does not show both geometrical and optical isomerism.(2) ⇒dsp2 hybridisation; shows geometrical isomerism but does not show optical isomerism.(3) ⇒d2sp3 hybridisation; shows both geometrical and optical isomerism.(4) ⇒d2sp3 hybridisation; does not show geometrical isomerism but shows optical isomerism.